The PS VR aim controller is a Bluetooth® device. You’ll need to pair your controller when you use it for the first time and when you use it with another PS4™ console.
With your PS4 system on, connect your controller using a micro USB cable*, then press the 2 PS button. Your controller pairs with the system and turns on. After you’ve paired your controller, you can disconnect the micro USB cable and use your controller wirelessly.
*The PS VR aim controller is not supplied with a micro-USB. Use the micro-USB cable for your DualShock 4 wireless controller.